Nonlinear systems on the example of zirconium oxyhydrate

Polymerization hydrated particles leads to the formation of thermodynamically metastable polymer fragments. With increasing chain length increases its instability, which in turn increases the probability of destruction of the circuit. At a certain length of its polymer chain rupture occurs. The resulting fracture fragments are more stable and can continue to grow once again. At rupture of polymer chains, structural water comes onto the surface and participates in the formation of elongated, diffuse DES. There is a periodic nature of these phenomena. Thus, the processes occurring in the gel during its aging, namely the consistent growth of polymer fragments, and their destruction, and conformational (PEPTIZATION-polymerization) transitions gel fragments, that is, the structuring and restructuring of the system, provide a temporary frequency properties of the gel. If we consider this periodicity ofproperties in terms of energy, we have the power ripple noise in gel systems. Noise vibrations of the system - are periodic temporal variations of the instantaneous dynamic viscosity within gels. As the analysis of the reconstructed attractors in the evolution of zirconium oxy-hydrate gel undergoes a series of structural transformations that cause the change of geometry and intensity of the current in oxyhydrate cluster ion flows. In addition, the nature of their symptoms is often changed. According to a particularly changes SPT (spontaneous pulsating current or current self-organization) in time (within two months of the life of the hydrogel). Using platinum or graphite electrodes can be divided into four time slots aged samples: the first (1-24 days), second (25-40 days), the third (41-54 days), the fourth (55-60 days). Relatively high values of current spikes may indicate a predominance of certain secondary processes "digested" polymerization or crosslinking of hydration, ie elongation gel macromolecules. The quantity of water of hydration of the gel sample either decreases or increases. It is set in the methods of thermogravimetry. At a certain critical length of the polymer chain must be her break. Two Resulting fragments are more stable and can continue to grow once again. At rupture of polymer chains, structural water comes onto the surface and participates in the formation of elongated, diffuse DES. This is quite understandable and pulsating nature of the phenomena of elimination of water. These reactions are found in the registration cluster ion spike flows in the electrochemical cell.

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