CO2 adsorption in different mesoporous ZSM-5 zeolites prepared with biomass
The adsorption of CO2 over porous materials seems to be the best solution to reduce the emissions of this gas into the atmosphere, that has been steadily increasing in the past few decades. With this process, it is possible to both adsorb the excess of CO2 present in the atmosphere as well as adsorbing CO2 from industrial wastes to avoid its emission. This can be achieved using different materials, such as aminebased compounds, activated carbons and zeolites. Moreover, the waste of biomass industry is also a concern among scientists, due to possible contamination of soils and water reservoirs. In this way, we present herein a comparative study of CO2 adsorption over different types of mesoporous zeolites prepared in the presence of biomass using post-treatment methods. The biomass selected was lignin from Russian wood waste, and its treated form (oxidized lignin). In this way, both CO2 and biomass waste are valorized, providing solutions for these two problems. The influence of the synthesis procedure in the zeolite crystallinity, type of pore created, and adsorption capacity was investigated. It was observed a constant crystallinity even when mesopores were created in the zeolite structure. Moreover, it was also observed an increased performance in the adsorption process when high mesopores size was present. By comparing these results with pristine commercial zeolite, we aim to provide useful insights on the factors that may influence the CO2 adsorption capacity over zeolites. With this new information, it may be possible to provide further strategies for adjusting their properties to obtain the better outcome of the process.
Keywords
CO2 adsorption,
zeolite,
mesoporous zeolites,
hierarchical porosity,
adsorption capacity,
CO2 адсорбция,
цеолит,
мезопористые цеолиты,
иерархическая пористость,
адсорбционная емкостьAuthors
| Bingre Rogéria | Universite de Strasbourg Strasbourg | rpamaral@unistra.fr |
| Zaitceva Olesia | Tomsk State University | zaitcevaolesia@gmail.com |
| Louis Benoît | Universite de Strasbourg Strasbourg | blouis@unistra.fr |
Всего: 3
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