Influence of Nickel Oxide on the Composition of Products of Catalytic Cracking of Heavy Oil of the Zyuzeevskoye Field | Vestnik Tomskogo gosudarstvennogo universiteta. Chimia – Tomsk State University Journal of Chemistry. 2022. № 28. DOI: 10.17223/24135542/28/2

Influence of Nickel Oxide on the Composition of Products of Catalytic Cracking of Heavy Oil of the Zyuzeevskoye Field

In this work, a study was made of the effect of nickel oxide on the composition and structure of products of catalytic cracking of heavy oil from the Zyuzeevskoye field. It was demonstrated that cracking in the presence of 0.2% nickel oxide makes it possible to increase the yield of light fractions by 25.5% and reduce the content of tarasphaltene components by 23.2% wt. compared to the original oil. In the process of catalytic upgrading, a decrease in the sulfur content in liquid products from 4.53% to 2.88 wt.% is observed. The phases of nickel sulfides Ni7S6, Ni9S8, and Ni0.96S were identified in the solid cracking products by XPA, which is the result of the interaction of nickel oxide with sulfur-containing compounds. ontribution of the authors: the authors contributed equally to this article. The authors declare no conflicts of interests.

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Keywords

heavy oil, nickel oxide, asphaltenes, nickel sulfide

Authors

Name	Organization	E-mail
Sviridenko Nikita N.	Institute of Petroleum Chemistry, Siberian Branch of the Russian Academy of Sciences	nikita26sviridenko@gmail.com
Urazov Khoshim Kh.	Institute of Petroleum Chemistry, Siberian Branch of the Russian Academy of Sciences	urazovhh@gmail.com
Sudarev Evgeniy A.	Tomsk Polytechnic University	sudarev@tpu.ru

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