The influence of crystalline salt hydrates in a fire extinguishing powder composition on its specific effectiveness in extinguishing flammable liquids | Tekhnologii bezopasnosti zhiznedeyatelnosti – Life Safety/Security Technologies. 2024. № 5. DOI: 10.17223/29491665/5/1

The influence of crystalline salt hydrates in a fire extinguishing powder composition on its specific effectiveness in extinguishing flammable liquids

The article presents the comparative evaluation of specific fire extinguishing efficiency of powder compositions containing crystalline hydrate salts as a gas-generating component. Thermodynamic calculations and experimental tests have shown a reduction in the consumption of powder compositions for extinguishing highly flammable liquids by at least 30% when hexahydrate of magnesium-ammonium phosphate MgNH4PO46H2O is used as a component of fire extinguishing powders. The research has shown the advantage of implementing fine particles of crystalline hydrates (d<10 µm) obtained during the controlled precipitation process compared to analogs manufactured by mechanical grinding (d < 100 µm). The authors declares no conflicts of interests.

Download file
Counter downloads: 10

Keywords

fire extinguishing powder composition, crystalline hydrates, specific extinguishing efficiency

Authors

NameOrganizationE-mail
Valtsifer Igor V.Institute of Technical Chemistry, Ural Branch of the Russian Academy of Sciences – branch of the Perm Federal Research Center, Ural Branch of the Russian Academy of Sciencesvaltsifer.i@itcras.ru
Shamsutdinov Artem S.Institute of Technical Chemistry, Ural Branch of the Russian Academy of Sciences – branch of the Perm Federal Research Center, Ural Branch of the Russian Academy of Sciencesshamsutdinov.a@itcras.ru
Valtsifer Viktor A.Institute of Technical Chemistry, Ural Branch of the Russian Academy of Sciences – branch of the Perm Federal Research Center, Ural Branch of the Russian Academy of Sciencesvaltsifer.v@itcras.ru
Strelnikov Vladimir N.Institute of Technical Chemistry, Ural Branch of the Russian Academy of Sciences – branch of the Perm Federal Research Center, Ural Branch of the Russian Academy of Sciencesinfo@itcras.ru
Всего: 4

References

Wang X. Study on Modification Technology of Superfine Dry Powder Fire Extinguishing Agent // Journal of Physics: Conference Series. 2023. P. 2539.
Nolan D. Handbook of fire and explosion protection engineering principles for oil, gas, chemical, and related facilities. Fourth Edition. Gulf Professional Publishing, 2019. P. 522.
Lapshin D.N., Kunin A.V., Semenov A.D. Influence of Chemical Impurities in Ammonium Phosphate and Ammonium Sulfate on the Properties of ABCE Fire Extinguishing Dry Powders // Russian Journal of General Chemistry. 2016. Vol. 86. P. 439-449. 10.1134/S 1070363216020444.
Xiaomin N., Chow W.K., Guangxuan L. Discussions on Applying Dry Powders to Suppress Tall Building Fires // Journal of applied fire science. 2009. Vol. 18. P. 155-191.
Kuang K., Huang X., Liao G. A Comparison between Superfine Magnesium Hydroxide Powders and Commercial Dry Powders on fire Suppression Effectiveness // Process Safety Environ. Protection. 2008. Vol. 86. P. 182-188.
Gurchumelia L., Tsarakhov M., Machaladze T., Tkemaladze S., Bejanov F., Chudakova O. Elaboration of New Types, Environmentally Safe Fire-Extinguishing Powders and Establish the Conditions of Extinguish Optimum and Effective Use of Such Powders // Modern Chemistry & Applications. 2018. Vol. 6. P. 257-266.
Haiqiang L., Ruowena Z., Jiaxina G., Siuming L., Yuana H. A Good Dry Powder to Suppress High Building Fires // APCBEE Proc. 2014. Vol. 9. P. 291-295.
Pat. CN102512779B. Dry powder fire extinguishing agent / Suzhou University (publ. date: 27.06.2012).
Patent US4149976A. Powder for extinguishing fires of liquid substances or of a mixture of liquid substances / Reuillon M., Mellottee H., Alfille L., Duco J., Fruchard Y., Malet J.-C., Chappellier A., Devillers B. Current Assignee: Commissariat a lEnergie Atomique et aux Energies Alternatives CEA (publ. date: 17.04.1976).
Патент 2277003 Российская Федерация. Огнетушащий порошковый состав / Вершинин С.Н. № 2004118342/15, заявл. 16.06.2004; опубл. 27.05.2006. Бюл. № 15. 11 с.
Zhang S., Shi H.-S., Huang S.-W., Zhang P. DehydrationCharacteristics of Struvite-K Pertaining to magnesium potassium phosphate cement System in Non-Isothermal Condition // Journal of thermal analysis and calorimetry. 2013. Vol. 111. P. 35-40.
Shih K., Yan H. The Crystallization of Struvite and its Analog (K-struvite) from Waste Streams for Nutrient Recycling // Environmental materials and waste. 2016. P. 665-686.
Siciliano A., Limonti C., Curcio G.M., Molinari R. Advances in Struvite Precipitation Technologies for Nutrients Removal and Recovery from Aqueous Waste and Wastewater // Sustainability. 2020. Vol. 12, № 18. P. 1-36.
Пьянкова А.В., Кондрашова Н.Б., Вальцифер И.В., Шамсутдинов А.Ш., Бормашенко Э.Ю. Синтез и термическое поведение мелкодисперсного порошкового огнегасящего агента на основе струвита // Неорганические материалы. 2021. Т. 57, № 10. С. 1144-1152.
Хуо Ян, Вальцифер И.В., Шамсутдинов А.Ш., Кондрашова Н.Б., Замащиков В.В., Пьянкова А.В. Синтез и применение гидрофобного диоксида кремния для улучшения реологических свойств огнетушащих составов на основе струвита // Физика горения и взрыва. 2023. Т. 59, № 6. С. 70-81.
Valtsifer I.V., Huo Y., Zamashchikov V.V., Shamsutdinov A.S., Kondrashova N.B., Sivtseva A.V., Pyankova A.V., Valtsifer V.A. Synthesis of Hydrophobic Nanosized Silicon Dioxide with a Spherical Particle Shape and Its Application in Fire-Extinguishing Powder Compositions Based on Struvite // Nanomaterials. 2023, Vol. 13. P. 1186.
ГОСТ 27331-87. Пожарная техника. Классификация.
ГОСТ Р 53280.4-2009. Установки пожаротушения автоматические. Огнетушащие вещества. Часть 4: Порошки огнетушащие общего назначения. Общие технические требования и методы испытаний.
НПБ 170-98. Порошки огнетушащие общего назначения. Общие технические требования. Методы испытаний.
ГОСТ Р 51057-2001. Техника пожарная. Огнетушители переносные. Общие технические требования. Методы испытаний.
Патент 2155088 Российская Федерация. Огнетушащий порошок многоцелевого назначения / Кущук В.А., Попов А.В., Суровцева Л.А., Чумаевский В.А. № 99104700/12, заявл. 11.03.1999; опубл. 27.08.2000. Бюл. № 24. 6 с.
 The influence of crystalline salt hydrates in a fire extinguishing powder composition on its specific effectiveness in extinguishing flammable liquids | Tekhnologii bezopasnosti zhiznedeyatelnosti – Life Safety/Security Technologies. 2024. № 5. DOI: 10.17223/29491665/5/1

The influence of crystalline salt hydrates in a fire extinguishing powder composition on its specific effectiveness in extinguishing flammable liquids | Tekhnologii bezopasnosti zhiznedeyatelnosti – Life Safety/Security Technologies. 2024. № 5. DOI: 10.17223/29491665/5/1

Download full-text version
Counter downloads: 68