Study of the optical spectra of 4-hydroxy-3-methoxibenzoic acid

Using electronic spectroscopy and quantum chemistry methods, the electronic spectra of vanillic acid in various solvents are interpreted. In the ground electronic state, four protolytic forms of vanillic acid in water were isolated: anionic, dianionic, cationic and neutral. In water, vanillin and isovaniline in the ground state have the same spectral characteristics: the absorption spectra coincide in position and intensity. Vanillic acid has a shift in the absorption and fluorescence bands compared with vanillin and isovaniline towards short wavelengths. The values of the minimum electrostatic potential indicate that vanillic acid has the deepest minimum in the region of the carbonyl oxygen atom. The study of fluorescence spectra showed that the radiative properties of the ionic forms of vanillic acid are different. The data of quantum chemical calculations indicate that electronic transitions in the molecule are formed with the participation of charge transfer from the phenyl part of the molecule to the oxygen atoms of the methoxy and carbonyl groups. The presence of OH, OCH3 and a carbonyl group in the structure of vanillic acid leads to the existence of a dianionic form, both in the ground and in the electronically excited states.

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