Thermal stability of the structure and optical properties of nanostructured TiO2 films | Izvestiya vuzov. Fizika. 2020. № 12. DOI: 10.17223/00213411/63/12/3

Thermal stability of the structure and optical properties of nanostructured TiO2 films

The structure and optical properties of the titanium dioxide films during annealing from 100 to 400 °C were studied. The films were obtained by ion-plasma high-frequency magnetron sputtering of polycrystalline rutile target in an argon atmosphere. It was shown that as-prepared TiO2 films are nanostructured with ~8 nm of rutile crystallite and ~ 3.3 Å of interplanar distance and contain a small fraction of anatase. Optical band gap of the films is 3.01 eV, the refractive index under normal conditions is 2.25. The films annealing from 100 to 400 °C practically does not change their structure, optical band gap and refractive index under normal conditions, i.e. the obtained nanostructured TiO2 films are thermal stable.

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Keywords

titanium dioxide films, ion-plasma sputtering, annealing, structure, optical band gap, refractive index

Authors

NameOrganizationE-mail
Mikhailova S.L.Al-Farabi Kazakh National Universitysvetik.mikhailova@gmail.com
Prikhodko O.Yu.Al-Farabi Kazakh National Universityoleg.prikhodko@kaznu.kz
Mukhametkarimov Ye.S.Al-Farabi Kazakh National Universitym.c.erzhan@mail.ru
Dauitkhan K.Al-Farabi Kazakh National Universitydkuansh@mail.ru
Doseke U.A.Al-Farabi Kazakh National Universityudoseke@mail.ru
Kozyukhin S.A.Kurnakov Institute of General and Inorganic Chemistry Russian Academy of Sciencessergkoz@igic.ras.ru
Kozik V.V.National Research Tomsk State Universityvkozik@mail.ru
Ismailova G.A.Al-Farabi Kazakh National Universityguzal_a81@mail.ru
Maksimova S.Ya.Al-Farabi Kazakh National Universitymak.son.21@mail.ru
Tarapeyeva A. Yu.Al-Farabi Kazakh National Universitytarapeyeva00@gmail.com
Zhakypov A.S.Al-Farabi Kazakh National Universityszhakypovalibek@gmail.com
Всего: 11

References

Diebold U. // Surf. Sci. Rep. - 2003. - V. 48. - P. 53-229.
Калыгина В.М., Новиков В.А., Петрова Ю.С. и др. // ФТП. - 2014. - Т. 48. - Вып. 7. - С. 989-994.
Singh R.S., Rangari V.K., Sanagapalli S., et al. // Sol. Energy Mater. Sol. Cells - 2004. - V. 82. Р. 315-330.
Ernst K., Belaidi A., and Konenkamp R. // Semicond. Sci. Technol. - 2003. - V. 18. - Р. 475-479.
Barrera M., Pla J., Bocchi C., and Migliori A. // Sol. Energ. Mat. Sol. C. - 2008. - V. 92. - Р. 1115-1122.
Комлев А.Е., Лапшин А.Е., Магдысюк О.В. и др.// Письма в ЖТФ. - 2010. - Т. 36. - Вып. 20. - С. 29-34.
Sun Sh., Song P., Cui J., and Liang Sh. // Catal. Sci. Technol. - 2019. - No. 9. - P. 4198.
Gajovic A. and Stubicar M. // J. Mol. Struct. - 2001. - V. 563-564. - P. 315-320.
Zhang J., Li M., Feng Zh., et al. // J. Phys. Chem. B. - 2006. - V. 110. - P. 927-935.
Orendorz A., Brodyanski A., Losch J., et al. // Surf. Sci. - 2007. - V. 601. - P. 4390-4394.
Kim D.W., Enomoto N., Nakagawa Z., and Kawamura K. // J. Am. Ceram. Soc. - 1996. - V. 79. - P. 1095-1099.
Swope R.J., Smyth J.R., and Larson A.C. // Am. Mineralogist. - 1995. - V. 80. - P. 448-453.
Jenkins R. and Snyder R.L. Introduction to X-Ray Powder Diffractometry. - N.Y.: Wiley, 1996. - Ser.: Chemical Analysis. V. 138. - 403 p.
Myers H.P. Introductory Solid State Physics. - London: Taylor & Francis, 2014. - 500 p.
Tayes J. // J. Non-Cryst. Sol. - 1966. - V. 15. - No. 1. - P. 627-630.
Ilican S., Caglar M., and Caglar Y. // Mater. Science-Poland. - 2007. - V. 25. - No. 3. - P. 709-718.
Брус В.В., Ковалюк Д., Марьянчук П.Д. // ЖТФ. - 2012. - Т. 82. - Вып. 8. - С. 110-113.
 Thermal stability of the structure and optical properties of nanostructured TiO<sub>2</sub> films | Izvestiya vuzov. Fizika. 2020. № 12. DOI: 10.17223/00213411/63/12/3

Thermal stability of the structure and optical properties of nanostructured TiO2 films | Izvestiya vuzov. Fizika. 2020. № 12. DOI: 10.17223/00213411/63/12/3