Prospects for producing hydrogen-ammonia fuel using lithium-aluminum amide
A statistical theory of the phase transformation of lithium aluminum amide with the release of ammonia is developed. The free energies of the phases are calculated, their dependence on temperature, pressure, hydrogen concentration and energy parameters is established. The phase diagram is built. The equations of the thermodynamic equilibrium state are calculated. Investigated isoprocesses in phases. The coefficients of rectangularity and uniformity of isotherms are obtained. A feature of the temperature dependence of the concentration of hydrogen in phases is established.
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Keywords
hydrogen, statistical theory, phase transformations, ammonia, lithium-aluminum amide, isothermsAuthors
| Name | Organization | |
| Schur D.V. | Institute of Materials Science National Academy of Sciences of Ukraine; Al-Farabi Kazakh National University | shurzag@materials.kiev.ua |
| Zaginainchenko S.Yu. | Institute of Materials Science National Academy of Sciences of Ukraine | shurzag@materials.kiev.ua |
| Veziroglu Afer | International Hydrogen Energy Association | ayfer@me.com |
| Veziroglu T.N. | International Hydrogen Energy Association | veziroglu@iahe.org |
| Gavrylyuk N.A. | Institute of Materials Science National Academy of Sciences of Ukraine | n_afanasiyivna@ukr.net |
| Zolotarenko A.D. | Institute of Materials Science National Academy of Sciences of Ukraine | alex.zolotarenko@gmail.com |
| Gabdullin M.T. | Kazakh-British Technical University; Al-Farabi Kazakh National University | gabdullin@physics.kz |
| Ramazanov T.S. | Al-Farabi Kazakh National University | tlekkabul.ramazanov@kaznu.kz |
| Zolotarenko Al.D. | Institute of Materials Science National Academy of Sciences of Ukraine | o.d.zolotarenko@gmail.com |
| Zolotarenko An.D. | Institute of Materials Science National Academy of Sciences of Ukraine | a.d.zolotarenko@gmail.com |
References
Jacobs H. and Jänichen K. // Z. Annorg. Allg. Chem. - 1985. - V. 531. - P. 125-139.
Nakamori Y., Kitahara G., and Orimo S. // J. Power Sources. - 2004. - V. 136. - P. 309-312.
Pinkerton F.E. // J. Alloys Compd. - 2005. - V. 400. - P. 76-82.
Meisner G.P., Schullin M.I., Balogh M.P., et al. // J. Phys. Chem. B. - 2006. - V. 110. - P. 4186-4192.
Kojima Y., Matsumoto M., Kawai Y., et al. // J. Phys. Chem. B. - 2006. - V. 110. - No. 19. - P. 9632-9636.
Janot R., Eymery J.-B., and Tarascon J.-M. // J. Phys. Chem. - 2007. - V. 111. - No. 5. - P. 2335- 2340.
Eymery J.-B., Truflandier L., Charpentier T., et al. // J. Alloys Compd. - 2010. - V. 503. - P. 194-203.
Ono T., Shimoda K., Tsubota M., et al. // J. Alloys Compd. - 2010. - V. 506. - P. 297-301.
Ono T., Shimoda K., Tsubota M., et al. // J. Phys. Chem. C. - 2011. - V. 115. - P. 10284-10201.
Hino S., Grove H., Ichikawa T., et al. // Int. J. Hydrogen Energy. - 2015. - V. 40. - P. 16938-16947.
Ikeda K., Otomo T., Ohshita H., et al. // Mater. Trans. - 2014. - V. 55. - No. 8. - P. 1129-1133.
Dovgaliuk I. and Filinchuk Y. // Int. J. Hydrogen Energy. - 2016. - V. 41. - P. 15489-15504.
Кузык Б.Н., Кушлин В.Н., Яковец Ю.В. На пути водородной энергетики. - М.: ИНЭС, 2005. - 156 c.
Захаров С.В. // Омский научный вестник. Энергетика. - 2007. - Т. 1. - № 54. - С. 158-161.
Смирнов А.А. Молекулярно-кинетическая теория металлов. - М.: Наука, 1966. - 488 с.
Lytvynenko Y.M. and Schur D.V. // Renewable Energy. - 1999. - V. 16. - No. 1-4. - P. 753-756.
Schur D.V., Dubovoy A.G., Zaginaichenko S.Yu., et al. // Abstracts of Int. Conf. on «Carbon’04», Providence, Rhode Island, USA, July 11-16. - 2004. - P. 187.
Isayev K.B. and Schur D.V. // Int. J. Hydrogen Energy. -1996. - V. 21. - No. 11-12. - P. 1129-1132.
Schur D.V., Liashenko A.A., Adejev V.M., et al. // Int. J. Hydrogen Energy. - 1995 - V. 20. - No. 5. - P. 405-407.
Matysina Z.A., Schur D.V., and Zaginaichenko S.Y. // Int. J. Hydrogen Energy. - 1996. - V. 21. - No. 11-12. - P. 1085-1089.
Anikina N.S., Zaginaichenko S.Y., Maistrenko M.I., et al. // Proc. of NATO ARW on HMSCCN, Sudak. - 2003. - V. 172. Series II. - P. 207-216.
Аникина Н.С., Кривущенко О.Я., Щур Д.В. и др. // Труды 9-й Междунар. конф. «Водородное материаловедение и химия углеродных наноматериалов», Севастополь, Крым, Украина, 5-11 сент. 2005 г. - 2005. - С. 848-849.
Матысина З.А., Загинайченко С.Ю., Щур Д.В и др. Водород в кристаллах. - Киев: «КИМ», 2017. - 1060 с.
