Excitations of rotational energy levels of ozone molecule O₃ by collisions with atoms of the noble gases (Ar and He) | Izvestiya vuzov. Fizika. 2021. № 7. DOI: 10.17223/00213411/64/7/162

Excitations of rotational energy levels of ozone molecule O₃ by collisions with atoms of the noble gases (Ar and He)

The scattering cross-sections on rotational energy levels of O₃ by collisions with atoms of the noble gases (Ar and He) were calculated using the two-body scheme implemented in the MOLSCAT2020 package. All energy levels of O₃ up to J _max = K _max = 5 and J _max = K _max = 7 were included that corresponds to 18 and 32 coupled channel equations. The dependences of the scattering cross-sections on the collision energy were analyzed and the most probable excited rotational states of O₃ were determined. The rate coefficients at the temperatures of 5-300 K were calculated. The construction of the radial part of the angular coefficients of the interaction potential is also discussed.

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Keywords

ozone, argon, helium, scattering cross-sections, rate coefficients, rotational energy levels, potential energy surface, collisional dynamics, ab initio

Authors

Name	Organization	E-mail
Egorov O.V.	National Research Tomsk State University; V.E. Zuev Institute of Atmospheric Optics of the Siberian Branch of the Russian Academy of Sciences	egrvoleg@gmail.com
Tretyakov A.K.	National Research Tomsk State University	dr.akim1998@yandex.ru

Всего: 2

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