Influence of carbon materials on the structure and phase composition of composite ceramics based on a multicomponent system Hf–Ti–B–C–N
The paper considers the effect of carbon on composite ceramics based on the multicomponent Hf-Ti-B-C-N system. The process of obtaining a composite material is based on high-temperature exothermic reactions. In this case, the elements Ti and Hf are subjected to vacuum sintering to form a solid solution (Ti, Hf) and are used as the initial components of the Hf-Ti-B-C mixture. Chemical production waste (carbon black) and graphite are used as carbon. The structure and phase composition of composite ceramics based on the Hf-Ti-B-C-N system are studied depending on the allotropic modifications of carbon (carbon black, graphite). The presented results demonstrate the fundamental possibility of obtaining composite ceramics (Hf,Ti)CN-(TiB2/TiC-TiB2) using powder metallurgy methods. It is shown that the use of thermally coupled synthesis and graphite as a carbon source promotes the formation of the TiC phase in the composite structure.
Keywords
composite ceramics, self-propagating high-temperature synthesis, structure, phase composition, hafnium carbonitride, titanium diboride, titanium carbideAuthors
| Name | Organization | |
| Evseev Nikolay S. | Tomsk State University | evseevns@gmail.com |
| Khrustalev Anton P. | Tomsk State University | tofik0014@gmail.com |
| Belchikov Ivan A. | Tomsk State University | ivan70422@gmail.com |
| Khmeleva Marina G. | Tomsk State University | khmelevamg@gmail.com |
| Zhukov Ilya A. | Tomsk State University | gofra930@gmail.com |
References
Influence of carbon materials on the structure and phase composition of composite ceramics based on a multicomponent system Hf–Ti–B–C–N | Izvestiya vuzov. Fizika. 2026. № 1. DOI: 10.17223/00213411/69/1/13